Wr. Folks et al., LIGHT-INDUCED PERIODIC LATTICE OF DEFECTS IN SMECTIC-A AND SMECTIC-C LIQUID-CRYSTALS - STRUCTURAL AND DYNAMICAL ASPECTS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 292, 1997, pp. 183-197
Structural and dynamical studies of optically-induced effects in SmA a
nd SmC liquid crystals are presented. The smectic materials are doped
with photosensitive molecules capable of trans-cis isomerization unde
r light illumination. Laser irradiation leads to the formation of stro
ngly scattering textures with periodical array of parabolic focal coni
c domains (PFCD's). What is most surprising is that the effect is caus
ed by a low-power (< 10 mW) He-Ne laser beam; its efficiency is highes
t in the visible part of the spectrum. The written information can be
erased by another beam with shorter wavelength, such as from an Ar las
er or a UV source. The PFCD's lattice can be stabilized by a polymeric
network. The most plausible mechanism of the light-induced effect is
compression/dilation of smectic layers caused by phototransformation o
f the molecules.