DILUTE POLYMER IN A LYOTROPIC LAMELLAR SYSTEM WITHOUT INTERACTION - APOSSIBLE DEPLETION FLOCCULATION EFFECT

Citation
M. Kleman et M. Singhzocchi, DILUTE POLYMER IN A LYOTROPIC LAMELLAR SYSTEM WITHOUT INTERACTION - APOSSIBLE DEPLETION FLOCCULATION EFFECT, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 292, 1997, pp. 351-360
Citations number
17
Categorie Soggetti
Crystallography
ISSN journal
1058725X
Volume
292
Year of publication
1997
Pages
351 - 360
Database
ISI
SICI code
1058-725X(1997)292:<351:DPIALL>2.0.ZU;2-E
Abstract
It has been observed that a swollen L-alpha phase (Surfactant: Cetylpy ridinium Chloride; Cosurfactant: Hexanol; Solvent: Brine) keeps (at le ast) metastable under the addition of a Dilute quantity of a neutral, flexible polymer (Polyacrylamide) in brine in a large domain of concen tration (Ref. 3a), however the periodicity of the lamellar phase suffe rs a strong decrease. We explain this phenomenon by a privileged swell ing of the polymer coils, under the effect of an osmotic pressure loca lized in the coil region.