HIGHLY REDUCED ORGANOMETALLICS - 42 - A NEW METHOD FOR THE SYNTHESES OF [V(CO)(6)](-) AND [V(PF3)(6)](-) INVOLVING ANTHRACENIDE MEDIATED REDUCTIONS OF VCL3(THF)(3)

Authors
BARYBIN MV POMIJE MK ELLIS JE
Citation
Mv. Barybin et al., HIGHLY REDUCED ORGANOMETALLICS - 42 - A NEW METHOD FOR THE SYNTHESES OF [V(CO)(6)](-) AND [V(PF3)(6)](-) INVOLVING ANTHRACENIDE MEDIATED REDUCTIONS OF VCL3(THF)(3), Inorganica Chimica Acta, 269(1), 1998, pp. 58-62
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
269
Issue
1
Year of publication
1998
Pages
58 - 62
Database
ISI
SICI code
0020-1693(1998)269:1<58:HRO-4->2.0.ZU;2-X
Abstract
A new mild (0 degrees C, 1 atm P) and high yield (70%) synthesis of [V (CO)(6)](-) by the sodium anthracenide mediated reductive carbonylatio n of VCl3(THF)(3) is presented. This same procedure is also shown to p rovide the first conventional, non-photolytic route to [V(PF3)(6)](-), a remarkably stable substance. Corresponding sodium naphthalenide red uctions provide much lower yields of these vanadates. (C) 1998 Elsevie r Science S.A.