COORDINATION CHEMISTRY OF PERHALOGENATED CYCLOPENTADIENES - XXII - REACTION OF TETRABROMODIAZOCYCLOPENTADIENE WITH SOME HALIDE BRIDGED RH(I), RU(II) AND RU(III) COMPLEXES - MOLECULAR-STRUCTURE OF [C5BR5]RH(COD), A COMPLEX WITH AN ETA(1),ETA(4)-COORDINATED CYCLOPENTADIENYL LIGAND

Authors
SUNKEL K STRAMM C LANG M KEMPINGER W HOFMANN J
Citation
K. Sunkel et al., COORDINATION CHEMISTRY OF PERHALOGENATED CYCLOPENTADIENES - XXII - REACTION OF TETRABROMODIAZOCYCLOPENTADIENE WITH SOME HALIDE BRIDGED RH(I), RU(II) AND RU(III) COMPLEXES - MOLECULAR-STRUCTURE OF [C5BR5]RH(COD), A COMPLEX WITH AN ETA(1),ETA(4)-COORDINATED CYCLOPENTADIENYL LIGAND, Inorganica Chimica Acta, 269(1), 1998, pp. 111-116
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
269
Issue
1
Year of publication
1998
Pages
111 - 116
Database
ISI
SICI code
0020-1693(1998)269:1<111:CCOPC->2.0.ZU;2-8
Abstract
The halide bridged complexes [CpRuBr2](n) and [(COD)Rh(mu-X)](2) (X = Cl, Br) react with tetrabromodiazocyclopentadiene C5Br4N2 to give the pentahalocyclopentadienyl complexes CpRu[C5Br5] (1a) and either [C5B r4Cl]Rh(COD) (2a) or [C5Br5]Rh(COD) (2b), respectively. Treatment of C 5Cl4N2 with [CpRuBr](4) or [(COD)Rh(mu-Br)](2) yields the analogous c omplexes LnM [C5Cl4Br] (LnM = CpRu (1b), (COD)Rh (2c)) in high yield. A crystal structure determination of 2b shows the cyclopentadienyl li gand in an unusual eta(1),eta(4)-bonding fashion. Crystals of 2b are o rthorhombic, space group Pnma, a = 10.86(2), b = 12.841(5), c = 11.972 (4) Angstrom, V = 1670(3) Angstrom(3), Z = 4, R1 = 5.81%, wR2 = 14.22% . (C) 1998 Elsevier Science S.A.