Using classical mechanics and classical field theory, we confirm that
the ponderomotive momentum exists as a counterpart of the ponderomotiv
e energy to form the ponderomotive four-momentum when an electron inte
racts with a light plane wave. As a solution to the equations of motio
n, a time-dependent four-momentum on the electron (rest) mass shell is
obtained in a coordinate-free form. By taking out the quiver motion,
we find that the nonoscillating part of the four-momentum is not on th
e electron mass shell. We show mathematically that the decomposition o
f the nonoscillating four-momentum into an on-mass-shell four-momentum
and a lightlike four-momentum along the light-propagation direction i
s unique. The time-component of the Lightlike four-momentum is exactly
the ponderomotive energy, while the space-component is the ponderomot
ive momentum. We discuss the critical role of the ponderomotive four-m
omentum in light-electron scattering processes due to the lightlike pr
operty and the uniqueness of the decomposition of a four-momentum. Two
pieces of experimental evidence of the ponderomotive momentum are ide
ntified in the discussion.