SURFACE AND BULK DIFFUSION OF HDO ON ULTRATHIN SINGLE-CRYSTAL ICE MULTILAYERS ON RU(001)

The kinetics of HDO Surface and bulk diffusion on ultrathin (25-192 BL ; 96-700 Angstrom) single-crystal (H2O)-O-16 ice multilayers were stud ied using a combination of laser-induced thermal desorption (LITD) pro bing and isothermal desorption depth-profiling. The single-crystal hex agonal ice multilayers were grown epitaxially on a single-crystal Ru(0 01) metal substrate with the basal (001) facet of ice parallel to the Ru(001) surface. HDO surface diffusion on the single-crystal ice multi layer was not observed within the resolution of the LITD experiment at T=140 K. These LITD surface diffusion experiments yielded an upper Li mit to the HDO surface diffusion coefficient of D-s less than or equal to 1x10(-9) cm(2)/s at T= 40 K. The bulk diffusion coefficients were measured along the c axis of the hexagonal ice crystal which is perpen dicular to the (001) plane. HDO was observed to diffuse readily into t he underlying (H2O)-O-16 ice multilayer. The measured HDO bulk diffusi on coefficients ranged from D = 2.2(+/-0.3)x10(-16) cm(2)/s to D=3.9(/-0.4)x10(-14) cm(2)/s over the temperature range from 153 to 170 K. T he HDO bulk diffusion coefficients-were measured for (H2O)-O-16 thickn esses of 25-192 BL (1 BL=1.06x10(15) molecules/cm(2)) and initial HDO adlayer thicknesses of 2-9 BL. The KDO bulk diffusion was independent of (H2O)-O-16 him thickness and initial HDO coverage. Arrhenius analys is of the temperature-dependent bulk diffusion coefficients yielded a diffusion activation energy of E-A =17.0+/-1.0 kcal/mol and a diffusio n preexponential of D-0=4.2(+/-0.8)x10(8) cm(2)/s. Compared with extra polations from macroscopic diffusion kinetics obtained earlier at temp eratures close to the melting point, these bulk diffusion coefficients are larger and may reflect the perturbation of the ultrathin ice film s induced by the nearby interfaces. The differences between these HDO diffusion kinetics and recently measured kinetics for (H2O)-O-16 indic ate that H/D exchange and molecular transport make comparable contribu tions to the HDO diffusion coefficient. (C) 1998 American Institute of Physics.