STRUCTURE AND STABILITY OF GASEOUS FLUORINE-BRIDGED HETERODIMERS AND HETEROPOLYMERS - (AF)(N)(MF3)(M), A'F2MF3 (A = H, LI, NA, K M = B, AL,FE, A' = BE, MG, MN, N,M = 1,2)

Citation
G. Scholz et R. Stosser, STRUCTURE AND STABILITY OF GASEOUS FLUORINE-BRIDGED HETERODIMERS AND HETEROPOLYMERS - (AF)(N)(MF3)(M), A'F2MF3 (A = H, LI, NA, K M = B, AL,FE, A' = BE, MG, MN, N,M = 1,2), Journal of fluorine chemistry, 86(2), 1997, pp. 131-142
Citations number
120
ISSN journal
00221139
Volume
86
Issue
2
Year of publication
1997
Pages
131 - 142
Database
ISI
SICI code
0022-1139(1997)86:2<131:SASOGF>2.0.ZU;2-B
Abstract
Starting from an overview of experimentally identified and quantum che mically calculated gaseous fluoride heterodimers and oligomers, it is the intention of the authors to survey the present knowledge on struct ures and stabilities of these complexes and to draw some consequences for experimental chemistry. General characteristics of gaseous halogen -bridged complexes are explained in Section 2. The present knowledge o n experimentally identified and quantum chemically calculated fluorine -bridged heterocomplexes is summarized in Section 3. Finally, stabilit ies and structures of fluoroaluminate complexes in the vapour phase ar e discussed in Section 4. The discussion is focused on fluoroaluminate complexes containing mono-, di- and trivalent cations. (C) 1997 Elsev ier Science S.A.