We investigate the conductivity variation with density of compacted va
pour-grown carbon fibre (VGCF). The results indicate a typical transit
ion between a non-linear domain at low compaction conditions and a reg
ime where the conductivity increases roughly linearly with density whe
n the sample is subjected to higher pressures. From a simple scaling a
rgument, we suggest that percolation theory can be consistently applie
d to represent the morphological changes of the disordered system duri
ng the compaction process. In addition, a characteristic percolating b
ehaviour has been detected from the results of conductivity experiment
s with a polymer composite of VGCF and polypropylene. In this case, an
observed percolation threshold below 1% in volume confirms the highly
structured nature of the conducting filler material.