The incommensurate modulation has been found in the hexagonal Cs3Bi2I9
, belonging to the A(3)B(2)X(9) family of the layered compounds. The s
econd order normal-incommensurate transition at T-i = 224 K is accompa
nied by the symmetry change P6(3)/mmc <-> P2(1)/m. The transition into
a ferroelastic incommensurate phase occurs at the zone center, accord
ing to the NQR and ultrasonic measurements. (C) 1998 Elsevier Science
Ltd.