In order to reveal the band structure of cubic boron phosphide a photo
-and electroreflectance study has been undertaken. Towards this end, e
pitaxial thin films of this III-V semiconductor are grown on silicon (
100) by chemical vapor deposition. Both modulated reflectance techniqu
es reveal a critical point at 4.25 eV. The value of this first direct
transition is more than 1 eV lower than previous reports, which are ba
sed on transmission spectra. (C) 1998 American Institute of Physics. [
S0021-8979(98)00203-5].