STUDIES ON PROTONATION OF POLY(N,N-DIMETH YLANILINE)

Authors
ZHANG RF ZHENG HP SHEN JC
Citation
Rf. Zhang et al., STUDIES ON PROTONATION OF POLY(N,N-DIMETH YLANILINE), Gaodeng xuexiao huaxue xuebao, 19(1), 1998, pp. 144-147
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
19
Issue
1
Year of publication
1998
Pages
144 - 147
Database
ISI
SICI code
0251-0790(1998)19:1<144:SOPOPY>2.0.ZU;2-9
Abstract
In this paper, we studied the protonation of poly(N,N-dimethylaniline) (PDMA) in two different acid media(sulfuric acid and trichloroacetic acid), Using UV-Vis and H-1 NMR measurements, we found that PDMA could present two types of protonated states, which depends on the acidity, It can be concluded that protons were added on nitrogen atoms, of sub stituent in the concentrated acid but on benzene ring of main chain in the moderate acid solution.