BI(III) AS NEW CATALYST FOR THE SELECTIVE HYDROLYSIS OF ESTERS

Citation
V. Leboisselier et al., BI(III) AS NEW CATALYST FOR THE SELECTIVE HYDROLYSIS OF ESTERS, Tetrahedron letters, 38(17), 1997, pp. 2981-2984
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
17
Year of publication
1997
Pages
2981 - 2984
Database
ISI
SICI code
0040-4039(1997)38:17<2981:BANCFT>2.0.ZU;2-N
Abstract
The selective hydrolysis of esters has been carried out in a reaction catalyzed by Bi(III)mandelate in DMSO. The reaction is specific of ary l esters. Competition tests resulted in the quantitative hydrolysis of p-nitrophenyl acetate in the presence of ethyl benzoate or other aryl acetates. (C) 1997 Published by Elsevier Science Ltd.