LEWIS-ACID SUPPORTED REACTIONS OF 1,3-BIS(SILYL)ALLYL COMPOUNDS WITH EPOXIDES - INTERMOLECULAR AND INTRAMOLECULAR VERSIONS

Authors
NOWAK A BOLTE O SCHAUMANN E
Citation
A. Nowak et al., LEWIS-ACID SUPPORTED REACTIONS OF 1,3-BIS(SILYL)ALLYL COMPOUNDS WITH EPOXIDES - INTERMOLECULAR AND INTRAMOLECULAR VERSIONS, Tetrahedron letters, 39(7), 1998, pp. 529-532
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
7
Year of publication
1998
Pages
529 - 532
Database
ISI
SICI code
0040-4039(1998)39:7<529:LSRO1C>2.0.ZU;2-H
Abstract
Easily available 1,3-bis(silyl)allyl compounds react with epoxides und er Lewis acid catalysis to give interesting synthetic building blocks. The course of reaction depends on the stabilization of cationic inter mediates by the silicon beta-effect. (C) 1998 Elsevier Science Ltd. Al l rights reserved.