GENERATION OF ALLYLIC TITANOCENE DERIVATIVES FROM VINYL HALIDES AND ACP2TICL2-ME3AL REAGENT SYSTEM

Authors
HANZAWA Y KOWASE N TAGUCHI T
Citation
Y. Hanzawa et al., GENERATION OF ALLYLIC TITANOCENE DERIVATIVES FROM VINYL HALIDES AND ACP2TICL2-ME3AL REAGENT SYSTEM, Tetrahedron letters, 39(7), 1998, pp. 583-586
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
7
Year of publication
1998
Pages
583 - 586
Database
ISI
SICI code
0040-4039(1998)39:7<583:GOATDF>2.0.ZU;2-3
Abstract
The reagent prepared in advance by stirring a mixture of a Cp2TiCl2-Me 3Al reagent system in the ratio of 1:4 in toluene for 3 days is found to be effective in generating allylic titanocene on treatment with vin yl halides in THF. (C) 1998 Elsevier Science Ltd. All rights reserved.