NEW CARBON RADICAL CHEMISTRY AS A MODEL FOR THE BIOGENESIS OF THE INTERIORIN KADSULIGNAN TYPE OF DIBENZOCYCLOOCTADIENE LIGNAN/

Authors
GREEN SP WHITING DA
Citation
Sp. Green et Da. Whiting, NEW CARBON RADICAL CHEMISTRY AS A MODEL FOR THE BIOGENESIS OF THE INTERIORIN KADSULIGNAN TYPE OF DIBENZOCYCLOOCTADIENE LIGNAN/, Journal of the Chemical Society. Perkin transactions. I, (2), 1998, pp. 193-201
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
2
Year of publication
1998
Pages
193 - 201
Database
ISI
SICI code
0300-922X(1998):2<193:NCRCAA>2.0.ZU;2-S
Abstract
Novel intramolecular radical spirocyclisation reactions in aromatic nu clei, 48-->49, 40-->22 and 34-->32, are presented, which mimic a key s tep in the proposed biosynthesis of the interiorins 2a-d, the kadsulig nans 3a,b and relatives.