PREPARATION AND REACTION OF 3,3,3-TRIFLUOROPROPIONDITHIOACETALS AS TRIFLUOROMETHYL-CONTAINING BUILDING-BLOCKS

Citation
Hp. Guan et al., PREPARATION AND REACTION OF 3,3,3-TRIFLUOROPROPIONDITHIOACETALS AS TRIFLUOROMETHYL-CONTAINING BUILDING-BLOCKS, Journal of the Chemical Society. Perkin transactions. I, (2), 1998, pp. 279-281
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
2
Year of publication
1998
Pages
279 - 281
Database
ISI
SICI code
0300-922X(1998):2<279:PARO3A>2.0.ZU;2-2
Abstract
The preparation and reaction of 3,3,3-trifluoropropiondithioacetals 5 as possible trifluoromethyl-containing synthons has been studied. The synthesis of alkyl 1-acetoxy-3,3,3-trifluoropropyl thioethers 6 from c ompounds 5 and the Lewis acid-mediated reactions of compounds 6 with e nol silyl ethers are also described.