Optical absorption at room temperature and electrical resistivity at t
emperatures between 200 and 320 K for (As.Te)(1-x)Se-x thin films (whe
re x = 0.20, 0.23, 0.27, 0.32 and 0.44) have been studied. Increasing
the Se content was found to increase the optical energy gap and the ac
tivation energy for conduction of the investigated films. The optical
energy gap of the As0.40Te0.40Se0.20 films was increased up to 1.21 eV
by increasing the film thickness to similar to 120 nm, while thermal
annealing at 480 K reduced it down to 0.83 eV. The decrease of the opt
ical gap is discussed on the basis of amorphous-crystalline transforma
tions.