PSEUDO-OXOCARBONS - THE FIRST COMPLEX OF THE 3,4-BIS(DICYANOMETHYLENE)-CYCLOBUTANE-1,2-DIONE DIANION (CDCB(2-)) - CRYSTAL-STRUCTURE OF [(CU-2(CDCB)(MECN)(2))(N)]

Authors
PENA C GALIBERT AM SOULA B FABRE PL BERNARDINELLI G CASTAN P
Citation
C. Pena et al., PSEUDO-OXOCARBONS - THE FIRST COMPLEX OF THE 3,4-BIS(DICYANOMETHYLENE)-CYCLOBUTANE-1,2-DIONE DIANION (CDCB(2-)) - CRYSTAL-STRUCTURE OF [(CU-2(CDCB)(MECN)(2))(N)], Journal of the Chemical Society. Dalton transactions, (2), 1998, pp. 239-242
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
2
Year of publication
1998
Pages
239 - 242
Database
ISI
SICI code
0300-9246(1998):2<239:P-TFCO>2.0.ZU;2-5
Abstract
Reaction of copper(Ir) ion with 3,4-bis(dicyanomethylene)cyclobutane-1 ,2-dione dianion (cdcb(2-)) led to a copper(I) complex, [(Cu-2(cdcb)(M eCN)(2)},(n)]. The crystal structure of this first complex of cdcb has been determined; it consists of layers of Cu-2(cdcb)(MeCN)(2) units p arallel to the nb planes. The redox system of this complex, investigat ed by electrochemistry and ESR spectroscopy, is formed by the dianion, the radical anion, the neutral species of cdcb and the Cu-I-Cu-II sys tem.