T. Jiang et al., VERY SOFT CHEMISTRY - ROOM-TEMPERATURE SELF-ASSEMBLY OF (DABCOH)(2)SN3S7, A MICROPOROUS LAYERED TIN(IV) SULFIDE, Advanced materials, 10(1), 1998, pp. 42
Self-assembled metal chalcogenide open-framework materials such as tha
t shown in the Figure-a projection on the [100] plane of the structure
of a microporous layered tin(IV) sulfide (DABCOH)(2)Sn3S7 (1), where
DABCOH denotes singly protonated 1,8-diazabicyclooctane - are of inter
est for chemical sensing applications. A ''very soft chemistry'', room
temperature synthesis of 1 is reported.