IR SPECTROSCOPY OF CH3CN-HCL ADDUCTS IN SILICALITE CHANNELS - A MODELSYSTEM FOR THE STUDY OF ACID-BASE REACTIONS IN ZEOLITES

Authors
PAZE C BORDIGA S SPOTO G LAMBERTI C ZECCHINA A
Citation
C. Paze et al., IR SPECTROSCOPY OF CH3CN-HCL ADDUCTS IN SILICALITE CHANNELS - A MODELSYSTEM FOR THE STUDY OF ACID-BASE REACTIONS IN ZEOLITES, Journal of the Chemical Society. Faraday transactions, 94(2), 1998, pp. 309-314
Citations number
48
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
94
Issue
2
Year of publication
1998
Pages
309 - 314
Database
ISI
SICI code
0956-5000(1998)94:2<309:ISOCAI>2.0.ZU;2-1
Abstract
The CH3CN ... HCl hydrogen-bonded complex has been synthesized in the channels of silicalite, a purely siliceous microporous material with t he MFI structure. The IR spectra of this complex show that the effect of the solid environment on the vibrational properties of CH3CN ... HC l adducts is significant and that the framework enhances the strength of the hydrogen bond.