REGIOCONTROL IN PALLADIUM-CATALYZED ALLYLIC ALKYLATION BY ADDITION OFLITHIUM IODIDE

Authors
KAWATSURA M UOZUMI Y HAYASHI T
Citation
M. Kawatsura et al., REGIOCONTROL IN PALLADIUM-CATALYZED ALLYLIC ALKYLATION BY ADDITION OFLITHIUM IODIDE, Chemical communications, (2), 1998, pp. 217-218
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1998
Pages
217 - 218
Database
ISI
SICI code
1359-7345(1998):2<217:RIPAAB>2.0.ZU;2-O
Abstract
Regioselectivity in the palladium-catalysed allylic alkylation of 1-ar ylprop-2-enyl acetates [ArCH(OAc)CH=CH2] or (E)-3-phenylprop-2-enyl ac etate (PhCH=CHCH2OAc) with sodium enolates of soft carbon nucleophiles is controlled by addition of a catalytic amount of lithium iodide to give lienar products [O-ArCH=CHCH(2)Nu] exclusively; their branch isom ers [ArCH(Nu)CH=CH2] were not detected.