A NOVEL DECOMPLEXATION OF PI-ALLYLTRICARBONYLIRON LACTONE COMPLEXES USING BOROHYDRIDE REAGENTS - A NEW ROUTE TO STEREODEFINED ACYCLIC 1,5-DIOLS AND 1,5,7-TRIOLS
Sv. Ley et al., A NOVEL DECOMPLEXATION OF PI-ALLYLTRICARBONYLIRON LACTONE COMPLEXES USING BOROHYDRIDE REAGENTS - A NEW ROUTE TO STEREODEFINED ACYCLIC 1,5-DIOLS AND 1,5,7-TRIOLS, Chemical communications, (2), 1998, pp. 229-230
pi-Allyltricarbonyliron lactone complexes undergo a highly stereoselec
tive decomplexation reaction on treatment with sodium triacetoxyborohy
dride to afford acyclic alcohols in excellent yields.