CLEAVAGE OF THE PT-S BOND OF THIOLATED TERPYRIDINE-PLATINUM(II) COMPLEXES BY COPPER(II) AND ZINC(II) IONS IN PHOSPHATE BUFFER

Authors
CHENG CC LU YL
Citation
Cc. Cheng et Yl. Lu, CLEAVAGE OF THE PT-S BOND OF THIOLATED TERPYRIDINE-PLATINUM(II) COMPLEXES BY COPPER(II) AND ZINC(II) IONS IN PHOSPHATE BUFFER, Chemical communications, (2), 1998, pp. 253-254
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1998
Pages
253 - 254
Database
ISI
SICI code
1359-7345(1998):2<253:COTPBO>2.0.ZU;2-Z
Abstract
Using the chelation of a triamine moiety and an S-bridged heterodinucl ear unit, cleavage of the Pt-S bond in the thiolate-platinum complexes , [Pt(terpy)(BAT)](4+) and [Pt(terpy)(AET)](+) is induced by adding tr ansition metals such as Cu2+ Or Zn2+ in phosphate buffer (pH 7-8) at r oom temp.