SYNTHESIS AND STRUCTURE OF -TO)(2)SB-3(MU-NCY)(3)(MU(3)-NCY))K.ETA(6)-C6H5ME] - A SANDWICH COMPLEX CONTAINING A UNIQUE SB-III NIDO CAGE ANION (CY=CYCLOHEXYL, C6H11)

Authors
BESWICK MA CHOI N HOPKINS AD MCPARTLIN M PAVER MA WRIGHT DS
Citation
Ma. Beswick et al., SYNTHESIS AND STRUCTURE OF -TO)(2)SB-3(MU-NCY)(3)(MU(3)-NCY))K.ETA(6)-C6H5ME] - A SANDWICH COMPLEX CONTAINING A UNIQUE SB-III NIDO CAGE ANION (CY=CYCLOHEXYL, C6H11), Chemical communications, (2), 1998, pp. 261-262
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1998
Pages
261 - 262
Database
ISI
SICI code
1359-7345(1998):2<261:SASO->2.0.ZU;2-P
Abstract
Reaction of the terminal NMe2 groups of the spiro antimony(III) imido anion [{(Me2N)Sb(mu-NCy)}(2)Sb](-) with (BuOH)-O-t results in major re arrangement in the Sb-N framework as witnessed in the structure of the sandwich complex [{((BuO)-O-t)(2)Sb-3(mu-NCy)(3)(mu(3)-NCy)}K .eta(6) -C6H5Me] 1, containing the novel nido cage anion [((BuO)-O-t)(2)Sb-3(m u-NCy)(3)(mu(3)-NCy)](-).