2 NEW NICKEL-DMIT-BASED MOLECULAR CONDUCTORS BASED ON HETEROLEPTIC POLYMETALLIC COMPLEXES - SYNTHESIS, STRUCTURES AND ELECTRICAL-PROPERTIES

Authors
SHENG TL WU XT ZHANG WJ WANG QM GAO XC LIN P
Citation
Tl. Sheng et al., 2 NEW NICKEL-DMIT-BASED MOLECULAR CONDUCTORS BASED ON HETEROLEPTIC POLYMETALLIC COMPLEXES - SYNTHESIS, STRUCTURES AND ELECTRICAL-PROPERTIES, Chemical communications, (2), 1998, pp. 263-264
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1998
Pages
263 - 264
Database
ISI
SICI code
1359-7345(1998):2<263:2NNMCB>2.0.ZU;2-O
Abstract
Two heteroleptic dmit complexes of polynuclear nickel(II), [NEt4](2)[N i-5(edt)(4)(dmit)(2)] and [AsPh4](2)[Ni-3(pdt)(2)(dmit)(2)]. 0.5MeOH ( dmit = 2-thione-1,3-dithiole-4,5-dithiolate, H(2)edt = ethane-1,2-dith iol, H(2)pdt = propane-1,2-dithiol) are synthesized and characterized by X-ray crystallography and display room-temperature conductivities o f 1.75 x 10(-4) and 1.52 x 10(-5) S cm(-1); this is the first report o f semiconducting heteroleptic dmit complexes consisting of more than t wo nickel(II) centres.