We report first on the essential contributions of Mossbauer spectromet
ry to investigate iron-based metallic glasses. In addition to the anal
ysis of the distributions of hyperfine data in terms of Fe coordinatio
n and neighbours, Mossbauer spectrometry is able to estimate the magne
tic anisotropy from the magnetic texture, which can be correlated to t
he solidification process. After an overview of the different physical
properties of the amorphous metallic alloys we also present their mos
t advanced applications.