ENANTIOSELECTIVE SYNTHESIS OF 24,25-DIHYDROXY VITAMIN-D-3 NORTHERN PORTION FROM (S)-3-HYDROXY-2,2-DIMETHYLCYCLOHEXANE-1-ONE - REMOTE ASYMMETRIC INDUCTION IN AN ACID-CATALYZED CONJUGATE ADDITION

Authors
STEPANENKO W WICHA J
Citation
W. Stepanenko et J. Wicha, ENANTIOSELECTIVE SYNTHESIS OF 24,25-DIHYDROXY VITAMIN-D-3 NORTHERN PORTION FROM (S)-3-HYDROXY-2,2-DIMETHYLCYCLOHEXANE-1-ONE - REMOTE ASYMMETRIC INDUCTION IN AN ACID-CATALYZED CONJUGATE ADDITION, Tetrahedron letters, 39(8), 1998, pp. 885-888
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
8
Year of publication
1998
Pages
885 - 888
Database
ISI
SICI code
0040-4039(1998)39:8<885:ESO2VN>2.0.ZU;2-C
Abstract
Enantioselective synthesis of building blocks, 2 and 16, for 24,25-dih ydroxy- and 25-hydroxy vitamin D synthesis, respectively, from easily accessible optically active hydroxy ketone 5, is described. (C) 1998 E lsevier Science Ltd. All rights reserved.