DIRECT SYNTHESIS OF TRANS-1,4-DIACETOXYCYCLOHEXA-2,5-DIENE BY ELECTROCHEMICAL REDUCTION OF R-1,T-4-DIACETOXY-T-2,C-3-DIBROMOCYCLOHEX-5-ENE

Authors
KELEBEKLI L DEMIR U KARA Y
Citation
L. Kelebekli et al., DIRECT SYNTHESIS OF TRANS-1,4-DIACETOXYCYCLOHEXA-2,5-DIENE BY ELECTROCHEMICAL REDUCTION OF R-1,T-4-DIACETOXY-T-2,C-3-DIBROMOCYCLOHEX-5-ENE, Journal of chemical research. Synopses, (11), 1997, pp. 402-403
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
11
Year of publication
1997
Pages
402 - 403
Database
ISI
SICI code
0308-2342(1997):11<402:DSOTBE>2.0.ZU;2-C
Abstract
Electrochemical reduction of r-1,t-4-diacetoxy-t-2,c-3-dibromocyclohex -5-ene 1 gives only trans-1,4-diacetoxycyclohexa-2,5-diene 2 in good y ield while the commonly used Zn reduction gives a product mixture cont aining 2 and acetoxybenzene 3 derived from acetoxy elimination.