ENVIRONMENTALLY FRIENDLY CATALYSIS USING SUPPORTED REAGENTS - ENHANCED SELECTIVITY WITHOUT LOSS IN ACTIVITY IN THE ALKYLATION OF BENZENE USING HEXAGONAL MESOPOROUS SILICA (HMS)-SUPPORTED ALUMINUM-CHLORIDE

Authors
CLARK JH PRICE PM MARTIN K MACQUARRIE DJ BASTOCK TW
Citation
Jh. Clark et al., ENVIRONMENTALLY FRIENDLY CATALYSIS USING SUPPORTED REAGENTS - ENHANCED SELECTIVITY WITHOUT LOSS IN ACTIVITY IN THE ALKYLATION OF BENZENE USING HEXAGONAL MESOPOROUS SILICA (HMS)-SUPPORTED ALUMINUM-CHLORIDE, Journal of chemical research. Synopses, (11), 1997, pp. 430-431
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
11
Year of publication
1997
Pages
430 - 431
Database
ISI
SICI code
0308-2342(1997):11<430:EFCUSR>2.0.ZU;2-X
Abstract
Substantial increases in selectivity towards monoalkylation of benzene with alkenes can be achieved through the use of mesoporous HMS as sup port for immobilised aluminium chloride and through the use of externa l site poisons while maintaining activities comparable to homogeneous AlCl3.