The application of non-linear optical methods nowadays allows the meas
urement of an increasing number of specific plasma quantities which we
re previously not amenable to diagnostics. Among those are state resol
ved measurements of molecular density distributions, sensitive measure
ment of light atomic radical densities, electric field measurements, a
nd determination of quenching rates. In this paper an overview of the
available techniques and trends is given. Some selected topics are dis
cussed in more detail.