PALLADIUM-CATALYZED COUPLING BETWEEN ALLYL CARBONATES AND TRIETHYL METHANETRICARBOXYLATE (TEMT)

Authors
CRAVOTTO G GIOVENZANA GB SISTI M PALMISANO G
Citation
G. Cravotto et al., PALLADIUM-CATALYZED COUPLING BETWEEN ALLYL CARBONATES AND TRIETHYL METHANETRICARBOXYLATE (TEMT), Tetrahedron, 54(8), 1998, pp. 1639-1646
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
8
Year of publication
1998
Pages
1639 - 1646
Database
ISI
SICI code
0040-4020(1998)54:8<1639:PCBACA>2.0.ZU;2-8
Abstract
Triethyl methanetricarboxylate (TEMT) is allylated by allylic carbonat es in the presence of catalytic amounts of Pd(0) complexes; the reacti on, conducted in very mild conditions, is fast and gives high yields o f the title products. (C) 1998 Elsevier Science Ltd. All rights reserv ed.