REDUCTION OF DITHIOACETALS WITH SMI2 IN BENZENE-HMPA

Authors
KUNISHIMA M NAKATA D HIOKI K TANI S
Citation
M. Kunishima et al., REDUCTION OF DITHIOACETALS WITH SMI2 IN BENZENE-HMPA, Chemical and Pharmaceutical Bulletin, 46(1), 1998, pp. 187-189
Citations number
24
Categorie Soggetti
Chemistry Medicinal",Chemistry,"Pharmacology & Pharmacy
Journal title
Chemical and Pharmaceutical Bulletin → ACNP
ISSN journal
00092363
Volume
46
Issue
1
Year of publication
1998
Pages
187 - 189
Database
ISI
SICI code
0009-2363(1998)46:1<187:RODWSI>2.0.ZU;2-D
Abstract
Partial reduction of dithioacetals to the corresponding sulfides was e ffected by samarium iodide in the presence of either t-BuOH or acetic acid in benzene-HMPA. An alpha-sulfenyl anion was shown to be involved .