ASYMMETRIC-SYNTHESIS OF STEROIDAL TROGERS BASE ANALOGS - X-RAY MOLECULAR-STRUCTURE OF METHYL 3-ALPHA,12-ALPHA-(6H, 12H-5,11-METHANODIBENZO[B,F][1,5] DIAZOCINE-2,8-BISACETOXY)-5-BETA-CHOLAN-24-OATE

Authors
MAITRA U BAG BG RAO P POWELL D
Citation
U. Maitra et al., ASYMMETRIC-SYNTHESIS OF STEROIDAL TROGERS BASE ANALOGS - X-RAY MOLECULAR-STRUCTURE OF METHYL 3-ALPHA,12-ALPHA-(6H, 12H-5,11-METHANODIBENZO[B,F][1,5] DIAZOCINE-2,8-BISACETOXY)-5-BETA-CHOLAN-24-OATE, Journal of the Chemical Society. Perkin transactions. I, (16), 1995, pp. 2049-2056
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
16
Year of publication
1995
Pages
2049 - 2056
Database
ISI
SICI code
0300-922X(1995):16<2049:AOSTBA>2.0.ZU;2-K
Abstract
Cyclization of compound 5c in trifluoroacetic acid/hexamethylenetetram ine produces Troger's base analogue 6c in 75% yield with 70% diastereo selectivity.