KINETICS AND MECHANISM OF CHROMIUM(III)-CATALYZED OXIDATION OF FORMIC-ACID BY CERIUM(IV) IN AQUEOUS SULFURIC-ACID MEDIA

Authors
SAHA PN MONDAL SK KAR D DAS M DAS AK MOHANTY RK
Citation
Pn. Saha et al., KINETICS AND MECHANISM OF CHROMIUM(III)-CATALYZED OXIDATION OF FORMIC-ACID BY CERIUM(IV) IN AQUEOUS SULFURIC-ACID MEDIA, Journal of chemical research. Synopses, (10), 1997, pp. 364-365
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
10
Year of publication
1997
Pages
364 - 365
Database
ISI
SICI code
0308-2342(1997):10<364:KAMOCO>2.0.ZU;2-R
Abstract
In the Cr-III-catalysed oxidation of formic acid by Ce-IV in aqueous s ulfuric acid media, an intermediate involving the oxidant, substrate a nd catalyst is formed and a Cr-III/Cr-IV catalytic cycle operates.