A. Watterich et al., MO5-H AND W5+-H CENTERS IN ZNWO4 SINGLE-CRYSTALS CHARACTERIZED BY ESRAND ENDOR SPECTROSCOPY(), Journal of physics. Condensed matter, 10(1), 1998, pp. 205-213
ESR and ENDOR methods are used to characterize a new Mo5+-H centre wit
h C-1 symmetry in reduced ZnWO4:Mo single crystals. Present ENDOR resu
lts also confirm that for the recently reported W5+-H centre in UV- or
gamma-irradiated ZnWO4:Li crystal an observed superhyperfine interact
ion results from a nearby hydrogen nucleus. Comparison of spin-Hamilto
nian parameters shows the similarity of Mo5+-H and W5+-H centres in Zn
WO4 crystals.