Sj. Benz et Nj. Scenna, THE INFLUENCE OF DIFFERENT MODELS IN OBTAINING MULTIPLE SOLUTIONS IN DISTILLATION-COLUMNS, Canadian journal of chemical engineering, 75(6), 1997, pp. 1142-1152
This paper is about the sensitivity of detection of multiple solutions
to the structures or parameters incorporated in the equation system t
hat represents a distillation column. The performance of different col
umn simulation models, generally carried out in commercial simulators,
is tested to detect multiplicity. The influence of the physicochemica
l estimating methods and the adopted numeric strategies to solve disti
llation problems is considered. Important behavioral differences have
been found according to the model, the calculation method and the ther
modynamic properties package used. Besides, the starting point is very
important in the search of the hysteresis loop.