The desire to use and control photons in a manner analogous to the con
trol of electrons in solids has inspired great interest in such topics
as the localization of light, microcavity quantum electrodynamics and
near-field optics(1-6). A fundamental constraint in manipulating ligh
t is the extremely low transmittivity of apertures smaller than the wa
velength of the incident photon, While exploring the optical propertie
s of submicrometre cylindrical cavities in metallic films, we have fou
nd that arrays of such holes display highly unusual zero-order transmi
ssion spectra (where the incident and detected light are collinear) at
wavelengths larger than the array period, beyond which no diffraction
occurs, In particular, sharp peaks in transmission are observed at wa
velengths as large as ten times the diameter of the cylinders. At thes
e maxima the transmission efficiency can exceed unity (when normalized
to the area of the holes), which is orders of magnitude greater than
predicted by standard aperture theory, Our experiments provide evidenc
e that these unusual optical properties are due to the coupling of lig
ht with plasmons-electronic excitations-on the surface of the periodic
ally patterned metal film, Measurements of transmission as a function
of the incident light angle result in a photonic band diagram, These f
indings may find application in novel photonic devices.