A NEW, GENERAL-ROUTE TO 1-CHLORO-1-ETHYNYLCYCLOPROPANES VIA CHLORO(TRIMETHYLSILYETHYNYL)CARBENE

Authors
SHAVRIN KN KRYLOVA IV SHVEDOVA IB NEFEDOV OM
Citation
Kn. Shavrin et al., A NEW, GENERAL-ROUTE TO 1-CHLORO-1-ETHYNYLCYCLOPROPANES VIA CHLORO(TRIMETHYLSILYETHYNYL)CARBENE, Mendeleev communications, (6), 1997, pp. 218-219
Citations number
17
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
6
Year of publication
1997
Pages
218 - 219
Database
ISI
SICI code
0959-9436(1997):6<218:ANGT1V>2.0.ZU;2-E
Abstract
A new, general route to 1-chloro-1 -ethynylcyclopropanes 6 has been de veloped via cycloaddition of previously unknown chloro(trimethylsilyle thynyl)carbene 4b to olefins with formation of the corresponding cyclo propanes 5a-f in 35-65% yield and subsequent removal of the trimethyls ilyl group under the action of KF-2H(2)O in aqueous DMF to give cyclop ropanes 6 in up to 80% yield.