A THEORETICAL-STUDY OF THE MECHANISM OF OXIDATIVE DIHYDROGEN ADDITIONTO PALLADIUM CLUSTERS

Authors
MAMAEV VM GLORIOZOV IP SIMONYAN VV ZERNOVA EV PRISYAJNYUK AV USTYNYUK YA
Citation
Vm. Mamaev et al., A THEORETICAL-STUDY OF THE MECHANISM OF OXIDATIVE DIHYDROGEN ADDITIONTO PALLADIUM CLUSTERS, Mendeleev communications, (6), 1997, pp. 246-248
Citations number
20
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
6
Year of publication
1997
Pages
246 - 248
Database
ISI
SICI code
0959-9436(1997):6<246:ATOTMO>2.0.ZU;2-I
Abstract
The mechanism of dihydrogen oxidative addition to the simplest palladi um cluster has been analysed within the framework of the reaction-path Hamiltonian approximation; a planar dihydride complex has been found to form without the potential energy barrier and intramolecular degene rate exchange of the protons in the complex has been investigated.