THERMOCHEMISTRY OF OXYGEN-ATOM TRANSFER FROM CP-ASTERISK-REO3

Authors
GABLE KP JULIETTE JJJ LI CB NOLAN SP
Citation
Kp. Gable et al., THERMOCHEMISTRY OF OXYGEN-ATOM TRANSFER FROM CP-ASTERISK-REO3, Organometallics, 15(24), 1996, pp. 5250-5251
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
24
Year of publication
1996
Pages
5250 - 5251
Database
ISI
SICI code
0276-7333(1996)15:24<5250:TOOTFC>2.0.ZU;2-V
Abstract
The reaction enthalpy for O atom transfer from CpReO3 to PPh(3) in to luene solution is measured to be -28.4 +/- 0.3 kcal/mol and -28.0 +/- 0.6 kcal/mol in THF solution. This allows the strength of the Re=O bon d in CpReO3 (in solution) to be estimated at 116.8 +/- 1.2 kcal/mol.