1-FLUOROGERMATRANE-GERMATRANE WITH THE SHORTEST INTRAMOLECULAR N-]GE BOND

Authors
LUKEVICS E BELYAKOV S ARSENYAN P POPELIS J
Citation
E. Lukevics et al., 1-FLUOROGERMATRANE-GERMATRANE WITH THE SHORTEST INTRAMOLECULAR N-]GE BOND, Journal of organometallic chemistry, 549(1-2), 1997, pp. 163-165
Citations number
15
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
549
Issue
1-2
Year of publication
1997
Pages
163 - 165
Database
ISI
SICI code
0022-328X(1997)549:1-2<163:1WTSIN>2.0.ZU;2-X
Abstract
1-Hydroxygermatrane readily reacts with boron trifluoride etherate in acetonitrile to give 1-fluorogermatrane in good yield. The length of t he N--> Ge donor-acceptor bond equals 2.011(9) Angstrom, which is the shortest among all studied for germatranes. (C) 1997 Elsevier Science S.A.