O-17 AND H-1-NMR CHEMICAL-SHIFTS OF HYDROXIDE AND HYDRONIUM ION IN AQUEOUS-SOLUTIONS OF STRONG ELECTROLYTES

Authors
MAEMETS V KOPPEL I
Citation
V. Maemets et I. Koppel, O-17 AND H-1-NMR CHEMICAL-SHIFTS OF HYDROXIDE AND HYDRONIUM ION IN AQUEOUS-SOLUTIONS OF STRONG ELECTROLYTES, Journal of the Chemical Society. Faraday transactions, 93(8), 1997, pp. 1539-1542
Citations number
19
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
93
Issue
8
Year of publication
1997
Pages
1539 - 1542
Database
ISI
SICI code
0956-5000(1997)93:8<1539:OAHCOH>2.0.ZU;2-S
Abstract
The O-17 and H-1 NMR chemical shifts of water [delta((OH2)-O-17), delt a((H2O)-H-1)] in aqueous solutions of NaCl, NaBr, NaI, NaNO3, NaClO4, NaOH, KCl, KBr, KNO3 and KOH have been measured and used to determine the delta(O-17), and delta(H-1) chemical shifts of hydroxide ion and s ome of its aqua-complexes. The delta(O-17), and delta(1H) chemical shi fts for the OH-...nH(2)O and H+...nH(2)O complexes are discussed.