Xh. Wu et al., STRUCTURAL ORIGIN OF V-DEFECTS AND CORRELATION WITH LOCALIZED EXCITONIC CENTERS IN INGAN GAN MULTIPLE-QUANTUM WELLS/, Applied physics letters, 72(6), 1998, pp. 692-694
In the growth of InGaN/GaN multiple quantum well (MQW) structures, a n
ovel defect (called the ''V-defect'') initiates at threading dislocati
ons in one of the first quantum wells in a MQW stack. This defect is c
ommon to almost all InGaN MQW heterostructures. The nature of the V-de
fect was evaluated using transmission electron microscopy (TEM), scann
ing TEM (STEM), and low-temperature cathodoluminescence (CL) on a seri
es of In0.20Ga0.80N/GaN MQW samples. The structure of the V-defect inc
ludes buried side-wall quantum wells (on the {<10(1)over bar 1>} plane
s) and an open hexagonal inverted pyramid which is defined by the six
{<10(1)over bar 1>} planes. Thus, in cross section this defect appears
as an open ''V''. The formation of the V-defect is kinetically contro
lled by reduced Ga incorporation on the pyramid walls ({<10(1)over bar
1>} planes). The V-defect is correlated with the localized excitonic
recombination centers that give rise to a long-wavelength shoulder in
photoluminescence (PL) and CL spectra. This long-wavelength shoulder h
as the following characteristics: (i) its intensity is correlated with
the side-wall quantum wells; (ii) the temperature independence of the
full width at half maximum strongly supports a localized exciton reco
mbination process. (C) 1998 American Institute of Physics.