REGIOSELECTIVE SYNTHESIS OF 2,2-DIMETHYLCYCLOPENTANONE USING 2-PYRROLIDONE MAGNESIUM SALT AS ELECTROGENERATED BASE

Authors
BONAFOUX D BORDEAU M BIRAN C DUNOGUES J
Citation
D. Bonafoux et al., REGIOSELECTIVE SYNTHESIS OF 2,2-DIMETHYLCYCLOPENTANONE USING 2-PYRROLIDONE MAGNESIUM SALT AS ELECTROGENERATED BASE, Synthetic communications, 28(1), 1998, pp. 93-98
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
1
Year of publication
1998
Pages
93 - 98
Database
ISI
SICI code
0039-7911(1998)28:1<93:RSO2U2>2.0.ZU;2-K
Abstract
An efficient, direct and regioselective preparation of 2,2-dimethylcyc lopentanone, via its enolate precursor regioselectively obtained using the 2-pyrrolidone magnesium salt, a base electrogenerated in DME/HMPA , is reported.