ALPHA-CHLORINATION OF KETONES WITH SODIUM-CHLORITE, MN(ACAC)(3) AND ALUMINA IN DICHLOROMETHANE

Authors
YAKABE S HIRANO M MORIMOTO T
Citation
S. Yakabe et al., ALPHA-CHLORINATION OF KETONES WITH SODIUM-CHLORITE, MN(ACAC)(3) AND ALUMINA IN DICHLOROMETHANE, Synthetic communications, 28(1), 1998, pp. 131-138
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
1
Year of publication
1998
Pages
131 - 138
Database
ISI
SICI code
0039-7911(1998)28:1<131:AOKWSM>2.0.ZU;2-T
Abstract
Chlorination of a variety of aliphatic, alicyclic, and aromatic ketone s with a reagent combination of NaClO2 and Mn(acac)(3) catalyst can be readily performed in dichloromethane to afford alpha-chloroketones in good yield under mild and neutral conditions with the aid of chromato graphic neutral alumina.