RADICAL REACTIONS OF ENONES WITH ELECTROPHILIC ALLYLSTANNANES

Citation
Ej. Enholm et al., RADICAL REACTIONS OF ENONES WITH ELECTROPHILIC ALLYLSTANNANES, Tetrahedron letters, 39(9), 1998, pp. 971-974
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
39
Issue
9
Year of publication
1998
Pages
971 - 974
Database
ISI
SICI code
0040-4039(1998)39:9<971:RROEWE>2.0.ZU;2-Y
Abstract
Reactions of allyltributylstannanes with enones were studied. Although the parent allylstannane would not react with enones, an electrophili c variation was successful. The reaction provides perhaps one of the o nly nonbasic and non-nucleophilic alternatives to the classic conjugat e additions. (C) 1998 Elsevier Science Ltd. All rights reserved.