DETAILED EXPERIMENTAL AND THEORETICAL-STUDY OF COLLISION-INDUCED DISSOCIATION OF NA-2(-2 TARGETS AT KEV ENERGIES() IONS ON HE AND H)

A combined experimental and theoretical investigation of collision-ind uced dissociation (CID) of the quasi-one-electron system Na-2(+) He at 80 eV center-of-mass energy is presented. This study, complemented by additional measurements with an H-2 target, provides a detailed analy sis of the competition between the two basic CID mechanisms: via excit ation of electronic states of the Na-2(+) molecular ion and via moment um transfer to one of the Na+ core. The experimental method is based o n a combined coincidence and time-of-flight technique, resulting in a complete measurement of the velocity vectors of the two fragments and giving a full determination of the collision parameters. The theoretic al analysis is based on the so-called nonadiabatic quantum molecular d ynamics, developed recently. This theory treats self-consistently and simultaneously classical atomic motion and quantum electronic transiti ons in dynamical processes of atomic many-body systems using time-depe ndent density functional theory. It allows one to simulate the experim ent in microscopic detail and. thus, provides a deep insight into the excitation and dissociation mechanism. The combined theoretical and ex perimental analysis can later be extended to more complex systems like larger molecules or clusters. [S1050-2947(98)04602-2].