In the present work a thermodynamic model is presented for the nucleat
ion of metastable Ag3Ge phase from the undercooled melt in Ag-Ge alloy
system. It is shown that under kinetically induced favourable conditi
on, nucleation of a single phase compound with an approximate stoichio
metry Ag3Ge has greater affinity for nucleation over Ag and Ge based p
hases requiring diffusion in the liquid.