Archaeometric methods such as provenance studies must be predicated on
understanding the processes that underlie the production of this info
rmation. This study focuses on element-based provenance studies of Mis
sissippian-period pottery, which are complicated by the fact that this
pottery generally war tempered with crushed shell in different amount
s and of unknown species composition. Experiments conducted at the Mis
souri University Research Reactor (MURR) have documented elemental dil
ution and enhancement effects of adding shell temper to clay. Mathemat
ical corrections previously have been employed to correct for shell-te
mper effects. Results of physical, chemical, and mathematical approach
es to eliminating the effects of shell tempering indicate that mathema
tical methods, based on a firm knowledge of shell composition provide
the most efficient correction.