Hj. Stein et al., HIGHLY PRECISE AND ACCURATE RE-OS AGES FOR MOLYBDENITE FROM THE EAST QINLING MOLYBDENUM BELT, SHAANXI PROVINCE, CHINA, Economic geology and the bulletin of the Society of Economic Geologists, 92(7-8), 1997, pp. 827-835
Isotope dilution with a modified alkali fusion procedure and negative
thermal ion mass spectrometry yields highly precise and accurate Re-Os
ages for molybdenite from two well-studied molybdenite deposits in th
e East Qinling molybdenum belt, China. Individual Re-Os ages carry a 2
sigma precision of +/-0.40 to 0.57 percent which includes a 0.31 perc
ent uncertainty in the Re-187 decay constant. For the unusual carbonat
ite-hosted Mo-Pb deposit at Huanglongpu, the weighted average of seven
analyses yields an age of 221.5 +/- 0.3 (0.15%) Ma. The weighted aver
age of two analyses of molybaenite from a porphyry Mo deposit at Jindu
icheng, about 10 km to the southwest, yields an age of 138.4 +/- 0.5 (
0.39%) Ma. These data provide uncertainties an order of magnitude less
than previous Re-Os ages. Molybdenite Re-Os ages are slightly older t
han ages obtained by other isotopic methods for genetically related ho
st-rock and vein material. It appears that the direct dating of sulfid
e, rather than altered host and vein material, may be critical to acqu
iring the correct age for mineralization. The East Qinling molybdenum
belt is part of a larger east-west-trending zone that marks the suture
between two major cratonic blocks. Consequently, the belt was a site
for Early-Middle Triassic compression (Indosinian orogeny) followed by
Jurassic-Cretaceous extension (Yenshanian orogeny). We suggest that t
he Huanglongpu and Jinduicheng deposits provide an analogue for proces
ses that may have been important in generating major molybdenum deposi
ts in the Colorado mineral belt. In Colorado, Late Cretaceous (Laramid
e) compression-related, alkalic magmatism was followed by Tertiary (Ri
o Grande) extension-related, granitic magmatism and the development of
major Climax-type porphyry Mo deposits. In particular, the Jinduichen
g deposit appears to be a nearly perfect match for Climax-type mineral
ization in Colorado. In contrast, the older Huanglongpu deposit may re
cord a mechanism whereby molybdenum is concentrated in the lower crust
. In both the Qinling molybdenum belt and the Colorado mineral belt, a
time gap of about 50 to 80 m.y. separates alkalic magmatism and excep
tionally evolved granitic magmatism.